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An overview of structural responses of helicenes with increasing dimensions and complexity to stepwise electron addition reveals charge- and topology-dependent outcomes ranging from reversible to irreversible core transformations and site-specific reactivity. 

A unique trimeric radical cation with unequal charge distribution is obtained by chemical oxidation of triphenylene with GaCl₃. XRD determined structure is combined with computational modeling showing stabilizing pancake bonding in the π-stacks. 

We present a generalization of the geometric phase to pure and thermal states in $$\mathcal{PT}$$-symmetric quantum mechanics (PTQM) based on the approach of the interferometric geometric phase (IGP). The formalism first introduces the parallel-transport conditions of quantum states and reveals two geometric phases, $$\theta^1$$ and $$\theta^2$$, for pure states in PTQM according to the states under parallel-transport. Due to the non-Hermitian Hamiltonian in PTQM, $$\theta^1$$ is complex and $$\theta^2$$ is its real part. The imaginary part of $$\theta^1$$ plays an important role when we generalize the IGP to thermal states in PTQM. The generalized IGP modifies the thermal distribution of a thermal state, thereby introducing effective temperatures. \textcolor{red}{At certain critical points, the generalized IGP may exhibit discrete jumps at finite temperatures, signaling a geometric phase transition. We illustrate the IGP of PTQM through two examples and compare their differences}. 

The high nuclearity cubane-assembled Mn-oxo clusters serve as effective precursors for the preparation of monodispersed Mn₃O₄nanocrystals through the colloidal chemistry approach. 

Artificial monopoles have been engineered in various systems, yet there has been no systematic study of the singular vector potentials associated with the monopole field. We show that the Dirac string, the line singularity of the vector potential, can be engineered, manipulated, and made manifest in a spinor atomic condensate. We elucidate the connection among spin, orbital degrees of freedom, and the artificial gauge, and show that there exists a mapping between the vortex filament and the Dirac string. We also devise a proposal where preparing initial spin states with relevant symmetries can result in different vortex patterns, revealing an underlying correspondence between the internal spin states and the spherical vortex structures. Such a mapping also leads to a new way of constructing spherical Landau levels, and monopole harmonics. Our observation provides insights into the behavior of quantum matter possessing internal symmetries in curved spaces. Published by the American Physical Society2024